Atkins' Physical ChemistryOxford University Press, 2018 - 908 páginas The exceptional quality of previous editions has been built upon to make this new edition of Atkins' Physical Chemistry even more closely suited to the needs of both lecturers and students. Re-organised into discrete Topics, the text is more flexible to teach from and more readable for students. Now in its eleventh edition, the text has been enhanced with additional learning features and maths support to demonstrate the absolute centrality of mathematics to physical chemistry. Increasing the digestibility of the text in this new approach, the reader is brought to a question, then the maths is used to show how it can be answered and progress made. The expanded and redistributed maths support also includes a greatly increased number of 'Chemist's toolkits' which provide students with succinct reminders of mathematical concepts and techniques right where they need them. Checklists of key concepts at the end of each Topic add to the extensive learning support provided throughout the book, to reinforce the main take-home messages in each section. The coupling of the broad coverage of the subject with a structure and use of pedagogy that is even more innovative will ensure Atkins' Physical Chemistry remains the textbook of choice for studying physical chemistry. |
Contenido
PROLOGUE Energy temperature and chemistry | 1 |
FOCUS 1 The properties of gases | 3 |
TOPIC 1A The perfect gas | 4 |
TOPIC 1B The kinetic model | 11 |
TOPIC 1C Real gases | 19 |
FOCUS 1 The properties of gases | 28 |
The First Law | 33 |
TOPIC 2A Internal energy | 34 |
FOCUS 5 Simple mixtures | 200 |
FOCUS 6 Chemical equilibrium | 203 |
TOPIC 6A The equilibrium constant | 204 |
TOPIC 6B The response of equilibria to the conditions | 212 |
TOPIC 6C Electrochemical cells | 217 |
TOPIC 6D Electrode potentials | 224 |
FOCUS 6 Chemical equilibrium | 229 |
FOCUS 16 Molecules in motion | 235 |
TOPIC 2B Enthalpy | 46 |
TOPIC 2C Thermochemistry | 51 |
TOPIC 2D State functions and exact differentials | 59 |
TOPIC 2E Adiabatic changes | 67 |
FOCUS 2 The First Law | 70 |
The Second and Third Laws | 77 |
TOPIC 3A Entropy | 78 |
TOPIC 3B Entropy changes accompanyingspecific processes | 88 |
TOPIC 3C The measurement of entropy | 92 |
TOPIC 3D Concentrating on the system | 97 |
TOPIC 3E Combining the First and Second Laws | 104 |
FOCUS 3 The Second and Third Laws | 111 |
FOCUS 4 Physical transformations of pure substances | 119 |
TOPIC 4A Phase diagrams of pure substances | 120 |
TOPIC 4B Thermodynamic aspects of phase transitions | 128 |
FOCUS 4 Physical transformations of pure substances | 135 |
FOCUS 4 Physical transformations of pure substances | 138 |
FOCUS 5 Simple mixtures | 141 |
TOPIC 5A The thermodynamic description of mixtures | 143 |
TOPIC 5B The properties of solutions | 155 |
liquids | 166 |
solids | 177 |
TOPIC 5E Phase diagrams of ternary systems | 180 |
TOPIC 5F Activities | 183 |
FOCUS 5 Simple mixtures | 191 |
liquids | 194 |
solids | 196 |
TOPIC 5E Phase diagrams of ternary systems | 198 |
TOPIC 5F Activities | 199 |
TOPIC 16A Transport properties of a perfect gas | 236 |
TOPIC 16B Motion in liquids | 245 |
FOCUS 16C Diffusion | 252 |
FOCUS 16 Molecules in motion | 261 |
FOCUS 17 Chemical kinetics | 267 |
TOPIC 17A The rates of chemical reactions | 269 |
TOPIC 17B Integrated rate laws | 277 |
TOPIC 17C Reactions approaching equilibrium | 283 |
TOPIC 17D The Arrhenius equation | 287 |
TOPIC 17E Reaction mechanisms | 292 |
TOPIC 17F Examples of reaction mechanisms | 299 |
TOPIC 17G Photochemistry | 308 |
FOCUS 17 Chemical kinetics | 315 |
FOCUS 18 Reaction dynamics | 325 |
TOPIC 18A Collision theory | 326 |
TOPIC 18B Diffusioncontrolled reactions | 333 |
TOPIC 18C Transitionstate theory | 338 |
TOPIC 18D The dynamics of molecular collisions | 347 |
TOPIC 18E Electron transfer in homogeneoussystems | 356 |
FOCUS 18 Reaction dynamics | 362 |
FOCUS 19 Processes at solid surfaces | 369 |
TOPIC 19A An introduction to solid surfaces | 370 |
TOPIC 19B Adsorption and desorption | 378 |
TOPIC 19C Heterogeneous catalysis | 387 |
TOPIC 19D Processes at electrodes | 391 |
FOCUS 19 Processes at solid surfaces | 401 |
RESOURCE SECTION | 407 |
| 437 | |
Otras ediciones - Ver todas
Atkins' Physical Chemistry 11e: Volume 3: Molecular Thermodynamics and Kinetics Peter Atkins,Julio De Paula,James Keeler Vista previa limitada - 2019 |
Atkins' Physical Chemistry PETER. DE PAULA ATKINS (JULIO. KEELER, JAMES.),Julio de Paula,James Keeler Sin vista previa disponible - 2018 |
Términos y frases comunes
activation energy activity coefficients adiabatic adsorbed adsorption atoms benzene boiling point Brief illustration Calculate cell potential chemical potential Collect your thoughts collision component composition constant pressure current density decreases dependence diffusion dm³ electron equilibrium constant example expansion experimental Figure flux follows function gases Gibbs energy given heat capacity increases initial integral internal energy ionic ions isotherm k₁ kinetic kJ mol¯¹ kJ mol−1 liquid measured mechanism mixture molar mass mole fraction molecular molecules overpotential partial pressure perfect gas phase diagram plot potential energy properties rate constant rate law reactants reaction Gibbs energy relation Resource section result reversible sample slope solid solution solvent species speed spontaneous standard enthalpy standard Gibbs energy standard potential standard reaction steady-state approximation step substance surface Table thermal thermodynamic tion Topic transfer v₁ vapour pressure Waals zero ΔΗ